Controlling Energy Levels and Blend Morphology for All-Polymer Solar Cells via Fluorination of a Naphthalene Diimide-Based Copolymer Acceptor
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Uddin, Mohammad Afsar | - |
dc.contributor.author | Kim, Youngkwon | - |
dc.contributor.author | Younts, Robert | - |
dc.contributor.author | Lee, Wonho | - |
dc.contributor.author | Gautam, Bhoj | - |
dc.contributor.author | Choi, Joonhyeong | - |
dc.contributor.author | Wang, Cheng | - |
dc.contributor.author | Gundogdu, Kenan | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.contributor.author | Woo, Han Young | - |
dc.date.accessioned | 2021-09-03T20:03:49Z | - |
dc.date.available | 2021-09-03T20:03:49Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2016-09-13 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/87526 | - |
dc.description.abstract | We investigate the photovoltaic properties and charge dynamics of all polymer solar cells (all-PSCs) based on poly[(N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl)-alt-5,5'-(2,2'-bithiophene)] (P-(NDI2OD-T2)) and its fluorinated analogue, poly[(N,N'-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl)-alt-5,5'-(3,3'-difluoro-2,2'-bithiophene)] (P-(NDI2OD-T2F)), as the acceptor polymer and poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophene-alt-5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione] (PBDTTTPD) as the donor polymer. The PBDTTTPD:P(NDI2OD-T2)-based device has a high open-circuit voltage (V-OC) of 1.03 V but suffers from low power conversion efficiency (PCE) of 2.02% with a short-circuit current density (J(SC)) and fill factor (FF) of 4.45 mA cm(2) and 0.44, respectively. In a stark contrast, the PCE of PBDTTTPD:P(NDI2OD-T2F)-based PSC dramatically increases to 6.09% (V-OC = 1.00 V, J(SC) = 11.68 mA cm(2), and FF = 0.52). These results are attributed to the fluorination, which removes the energetic barrier for hole transfer and promotes the formation of the donor/acceptor blend morphology with suppressed phase separation and enhanced intermixed phases. The detailed charge dynamics examined by femtosecond transient absorption spectroscopy suggests the significantly increased hole transfer efficiency and larger populations of long-lived polarons for PBDTTTPD:P(NDI2OD-T2F). | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | OPEN-CIRCUIT VOLTAGE | - |
dc.subject | POWER CONVERSION EFFICIENCY | - |
dc.subject | N-TYPE POLYMER | - |
dc.subject | HIGH-PERFORMANCE | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | PHOTOVOLTAIC CELLS | - |
dc.subject | MOLECULAR-ORIENTATION | - |
dc.subject | INTERFACIAL-TENSION | - |
dc.subject | ELECTRON-TRANSPORT | - |
dc.subject | ADDITIVE-FREE | - |
dc.title | Controlling Energy Levels and Blend Morphology for All-Polymer Solar Cells via Fluorination of a Naphthalene Diimide-Based Copolymer Acceptor | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.identifier.doi | 10.1021/acs.macromol.6b01414 | - |
dc.identifier.scopusid | 2-s2.0-84987670190 | - |
dc.identifier.wosid | 000383318300024 | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.49, no.17, pp.6374 - 6383 | - |
dc.relation.isPartOf | MACROMOLECULES | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 49 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 6374 | - |
dc.citation.endPage | 6383 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | OPEN-CIRCUIT VOLTAGE | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | N-TYPE POLYMER | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | PHOTOVOLTAIC CELLS | - |
dc.subject.keywordPlus | MOLECULAR-ORIENTATION | - |
dc.subject.keywordPlus | INTERFACIAL-TENSION | - |
dc.subject.keywordPlus | ELECTRON-TRANSPORT | - |
dc.subject.keywordPlus | ADDITIVE-FREE | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.