Surface mechanical properties of poly(urethane acrylate)/silica hybrid interpenetrating polymer network (IPN) coatings
- Authors
- Um, Min Seop; Ham, Dong Seok; Cho, Seong Keun; Lee, Sang-Jin; Kim, Kwang Je; Lee, Jae Heung; Choa, Sung-Hoon; Jung, Hyun Wook; Choi, Woo Jin
- Issue Date
- 8월-2016
- Publisher
- ELSEVIER SCIENCE SA
- Keywords
- Hard coating film; Nano-indentation test; Pencil hardness test; Nano-scratch test; Failure strain during stretching test; Dissipative and elastic energy ratios
- Citation
- PROGRESS IN ORGANIC COATINGS, v.97, pp.166 - 174
- Indexed
- SCIE
SCOPUS
- Journal Title
- PROGRESS IN ORGANIC COATINGS
- Volume
- 97
- Start Page
- 166
- End Page
- 174
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/88005
- DOI
- 10.1016/j.porgcoat.2016.04.007
- ISSN
- 0300-9440
- Abstract
- Surface mechanical properties of poly(urethane acrylate) (PUA)/silica hybrid interpenetrating polymer network (IPN) coating materials were investigated using several test methods including nano indentation, nano-scratch, pencil hardness, and stretching. To prepare coated films, an organic part (urethane acrylate) was mixed with an inorganic part (silica) at various ratios. Independent crosslinking reactions were applied to form the hybrid IPN structure: UV curing and sol-gel reactions were used for the organic and inorganic parts, respectively. The prepared hybrid IPN coatings exhibited no macroscopic phase separation. As the silica content was increased, the values for indentation hardness and pencil hardness increased, while failure strain during stretching test decreased. It was found that the hybrid IPN coating with its balanced dissipative and elastic properties had better scratch resistance than that of other coatings. (C) 2016 Elsevier B.V. All rights reserved.
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Collections - College of Engineering > Department of Chemical and Biological Engineering > 1. Journal Articles
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