Side Chain Optimization of Naphthalenediimide-Bithiophene-Based Polymers to Enhance the Electron Mobility and the Performance in All-Polymer Solar Cells
DC Field | Value | Language |
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dc.contributor.author | Lee, Wonho | - |
dc.contributor.author | Lee, Changyeon | - |
dc.contributor.author | Yu, Hojeong | - |
dc.contributor.author | Kim, Dong-Jun | - |
dc.contributor.author | Wang, Cheng | - |
dc.contributor.author | Woo, Han Young | - |
dc.contributor.author | Oh, Joon Hak | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.date.accessioned | 2021-09-04T01:46:52Z | - |
dc.date.available | 2021-09-04T01:46:52Z | - |
dc.date.created | 2021-06-17 | - |
dc.date.issued | 2016-03-08 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/89227 | - |
dc.description.abstract | Tuning the side chains of conjugated polymers is a simple, yet effective strategy for modulating their structural and electrical properties, but their impact on n-type conjugated polymers has not been studied extensively, particularly in the area of all-polymer solar cells (all-PSCs). Herein, the effects of side chain engineering of P(NDI2OD-T2) polymer (also known as Polyera Activink N2200) are investigated, which is the most widely used n-type polymer in all-PSCs and organic field-effect transistors (OFETs), on their structural and electronic properties. A series of naphthalenediimide-bithiophene-based copolymers (P(NDIR-T2)) is synthesized, with different side chains (R) of 2-hexyldecyl (2-HD), 2-octyldodecyl (2-OD), and 2-decyltetradecyl (2-DT). The P(NDI2HD-T2) exhibits more noticeable crystalline behaviors than P(NDI2OD-T2) and P(NDI2DT-T2), thereby facilitating superior 3D charge transport. For example, the P(NDI2HD-T2) shows the highest OFET electron mobility (1.90 cm(2) V-1 s(-1)). Also, a series of all-PSCs is produced using different electron donors of PTB7-Th, PTB7, and PPDT2FBT. The P(NDI2HD-T2) based all-PSCs produce much higher power conversion efficiency (PCE) irrespective of the electron donors. In particular, the PTB7-Th: P(NDI2HD-T2) forms highly ordered, strong face-on interchain stackings, and has better intermixed bulk-heterojunction morphology, producing the highest PCE of 6.11% that has been obtained by P(NDIR-T2) based all-PSCs to date. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | POWER CONVERSION EFFICIENCY | - |
dc.subject | THIN-FILM TRANSISTORS | - |
dc.subject | MOLECULAR-ORIENTATION | - |
dc.subject | CONJUGATED POLYMER | - |
dc.subject | BULK HETEROJUNCTIONS | - |
dc.subject | CHARGE-TRANSPORT | - |
dc.subject | BLEND MORPHOLOGY | - |
dc.subject | ADDITIVE-FREE | - |
dc.subject | CRYSTALLINITY | - |
dc.subject | AGGREGATION | - |
dc.title | Side Chain Optimization of Naphthalenediimide-Bithiophene-Based Polymers to Enhance the Electron Mobility and the Performance in All-Polymer Solar Cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.identifier.doi | 10.1002/adfm.201504191 | - |
dc.identifier.scopusid | 2-s2.0-84956699711 | - |
dc.identifier.wosid | 000372309000005 | - |
dc.identifier.bibliographicCitation | ADVANCED FUNCTIONAL MATERIALS, v.26, no.10, pp.1543 - 1553 | - |
dc.relation.isPartOf | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.title | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.volume | 26 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 1543 | - |
dc.citation.endPage | 1553 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | THIN-FILM TRANSISTORS | - |
dc.subject.keywordPlus | MOLECULAR-ORIENTATION | - |
dc.subject.keywordPlus | CONJUGATED POLYMER | - |
dc.subject.keywordPlus | BULK HETEROJUNCTIONS | - |
dc.subject.keywordPlus | CHARGE-TRANSPORT | - |
dc.subject.keywordPlus | BLEND MORPHOLOGY | - |
dc.subject.keywordPlus | ADDITIVE-FREE | - |
dc.subject.keywordPlus | CRYSTALLINITY | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordAuthor | all-polymer solar cells | - |
dc.subject.keywordAuthor | naphthalenediimide | - |
dc.subject.keywordAuthor | P(NDI2OD-T2) | - |
dc.subject.keywordAuthor | Polyera Acitivink N2200 | - |
dc.subject.keywordAuthor | side chain engineering | - |
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