Diastereomeric Resolution of a Racemic Biarylboronic Acid and Its Application to Divergent Asymmetric Total Syntheses of Some Axially Chiral Natural Products
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Chun-Young | - |
dc.contributor.author | Cheon, Cheol-Hong | - |
dc.date.accessioned | 2021-09-04T02:46:13Z | - |
dc.date.available | 2021-09-04T02:46:13Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2016-02-18 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/89500 | - |
dc.description.abstract | The asymmetric total syntheses of deshydroxytetramethylcupressuflavone and desmethylkotanin and the synthesis of a key intermediate in the previous synthesis of hibarimicinone are described using an axially chiral biarylboronic acid, prepared by the diastereomeric resolution of the corresponding rac-boronic acid, as a common intermediate. Conversion of the boronic acid moiety into either a hydrogen atom or a hydroxy group by protodeboronation or oxidation enabled us to complete the total syntheses of deshydroxytetramethylcupressuflavone and desmethylkotanin and synthesis of a key intermediate in the previous total synthesis of hibarimicinone, respectively. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | BIARYL SYNTHESIS | - |
dc.subject | BORONIC ACIDS | - |
dc.subject | KOTANIN | - |
dc.subject | PROTODEBORONATION | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | HIBARIMICINONE | - |
dc.subject | ASSIGNMENT | - |
dc.subject | ARYLATION | - |
dc.subject | LACTONES | - |
dc.subject | STRATEGY | - |
dc.title | Diastereomeric Resolution of a Racemic Biarylboronic Acid and Its Application to Divergent Asymmetric Total Syntheses of Some Axially Chiral Natural Products | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cheon, Cheol-Hong | - |
dc.identifier.doi | 10.1002/adsc.201500798 | - |
dc.identifier.scopusid | 2-s2.0-84958817873 | - |
dc.identifier.wosid | 000371665800008 | - |
dc.identifier.bibliographicCitation | ADVANCED SYNTHESIS & CATALYSIS, v.358, no.4, pp.549 - 554 | - |
dc.relation.isPartOf | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.title | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.volume | 358 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 549 | - |
dc.citation.endPage | 554 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | BIARYL SYNTHESIS | - |
dc.subject.keywordPlus | BORONIC ACIDS | - |
dc.subject.keywordPlus | KOTANIN | - |
dc.subject.keywordPlus | PROTODEBORONATION | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | HIBARIMICINONE | - |
dc.subject.keywordPlus | ASSIGNMENT | - |
dc.subject.keywordPlus | ARYLATION | - |
dc.subject.keywordPlus | LACTONES | - |
dc.subject.keywordPlus | STRATEGY | - |
dc.subject.keywordAuthor | axially chiral natural products | - |
dc.subject.keywordAuthor | boronic acids | - |
dc.subject.keywordAuthor | diastereomeric resolution | - |
dc.subject.keywordAuthor | MIDA boronates | - |
dc.subject.keywordAuthor | total synthesis | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.