Two- and three-dimensional Zn(II) coordination polymers constructed from mixed ligand systems: interpenetration, structural transformation and sensing behavior
DC Field | Value | Language |
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dc.contributor.author | Park, Min Kyung | - |
dc.contributor.author | Lim, Kwang Soo | - |
dc.contributor.author | Park, Ji Hey | - |
dc.contributor.author | Song, Jeong Hwa | - |
dc.contributor.author | Kang, Dong Won | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2021-09-04T05:06:06Z | - |
dc.date.available | 2021-09-04T05:06:06Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2016 | - |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/90189 | - |
dc.description.abstract | Four Zn(II) coordination compounds (1-4) were prepared solvothermally by reacting Zn2+ ions and organic linkers of dim and carboxylic acid-based ligands. Two-dimensional structures (1 and 2), which are extended to three-dimensional frameworks with the assistance of multiple hydrogen bonding interactions, are formed by employing isophthalate-based organic ligands. 4-fold (3) and 3-fold (4) interpenetrations occur when organic linkers that have carboxylic acid groups located oppositely are used. Interestingly, the interpenetrating nets undergo phase transformation via two pathways involving solvent exchange/resolvation and solvent exchange/activation/resolvation, which reveals that the structures are flexible. Photoluminescence properties show the selective fluorescence quenching of 3 and 4 in nitrobenzene (NB) among the tested solvents. Such quenching is substantial even at low NB concentrations, which is associated with the existence of Lewis basic sites in the interpenetrating framework. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | METAL-ORGANIC FRAMEWORKS | - |
dc.subject | HYDROGEN STORAGE | - |
dc.subject | CATENATION ISOMERISM | - |
dc.subject | CARBON-DIOXIDE | - |
dc.subject | FLEXIBILITY | - |
dc.subject | SORPTION | - |
dc.subject | NETWORKS | - |
dc.subject | LUMINESCENCE | - |
dc.subject | NITROBENZENE | - |
dc.subject | TEMPERATURE | - |
dc.title | Two- and three-dimensional Zn(II) coordination polymers constructed from mixed ligand systems: interpenetration, structural transformation and sensing behavior | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1039/c6ce00155f | - |
dc.identifier.scopusid | 2-s2.0-84973618763 | - |
dc.identifier.wosid | 000378237500017 | - |
dc.identifier.bibliographicCitation | CRYSTENGCOMM, v.18, no.23, pp.4349 - 4358 | - |
dc.relation.isPartOf | CRYSTENGCOMM | - |
dc.citation.title | CRYSTENGCOMM | - |
dc.citation.volume | 18 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 4349 | - |
dc.citation.endPage | 4358 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | CATENATION ISOMERISM | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | FLEXIBILITY | - |
dc.subject.keywordPlus | SORPTION | - |
dc.subject.keywordPlus | NETWORKS | - |
dc.subject.keywordPlus | LUMINESCENCE | - |
dc.subject.keywordPlus | NITROBENZENE | - |
dc.subject.keywordPlus | TEMPERATURE | - |
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