ScholarWorks@Korea University

Detailed Information

Cited 0 time in webofscience Cited 0 time in scopus
Metadata Downloads

New types of charge-compensated metallacarboranes: Synthesis, characterization, and structural studies of [(eta(5)-RC2B9H9CH2NMe2) Cr(mu-Cl)Cl](2) (R = H, Me)

Full metadata record
DC Field Value Language
dc.contributor.authorKang, Sang Ook-
dc.contributor.authorLee, Jong-Dae-
dc.date.accessioned2021-09-04T09:46:16Z-
dc.date.available2021-09-04T09:46:16Z-
dc.date.created2021-06-18-
dc.date.issued2015-12-01-
dc.identifier.issn0022-328X-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/91630-
dc.description.abstractCharge-compensated dicarbollyl chromium complexes of the type [(eta(5)-RC2B9H9 CH2NMe2)Cr(mu-Cl)Cl](2) (R = 5 and Me 6) were produced by reacting dicarbollylamino aluminum compounds [(mu(5)-RC2B9H9)(eta(1)-CH2NMe2)AlMe] with CrCl3 center dot THF3 in toluene solvent. This new complex is a relatively rare example of a dicarbollylchromium(III) complex containing unpaired electrons. An X-ray crystallographic investigation of 6 reveals a three-legged piano stool structure with a planar dichromium Cr unit containing bridged chloride ions. (C) 2015 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectSANDWICH CHROMIUM(III) COMPLEXES-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectCATALYTIC-PROPERTIES-
dc.subjectMETAL-COMPLEXES-
dc.subjectLIGANDS-
dc.subjectSALTS-
dc.subjectCHEMISTRY-
dc.subjectDICARBOLLYLAMINO-
dc.subjectDERIVATIVES-
dc.subjectREACTIVITY-
dc.titleNew types of charge-compensated metallacarboranes: Synthesis, characterization, and structural studies of [(eta(5)-RC2B9H9CH2NMe2) Cr(mu-Cl)Cl](2) (R = H, Me)-
dc.typeArticle-
dc.contributor.affiliatedAuthorKang, Sang Ook-
dc.identifier.doi10.1016/j.jorganchem.2015.06.025-
dc.identifier.scopusid2-s2.0-84949529974-
dc.identifier.wosid000366155400019-
dc.identifier.bibliographicCitationJOURNAL OF ORGANOMETALLIC CHEMISTRY, v.798, pp.121 - 124-
dc.relation.isPartOfJOURNAL OF ORGANOMETALLIC CHEMISTRY-
dc.citation.titleJOURNAL OF ORGANOMETALLIC CHEMISTRY-
dc.citation.volume798-
dc.citation.startPage121-
dc.citation.endPage124-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusSANDWICH CHROMIUM(III) COMPLEXES-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusCATALYTIC-PROPERTIES-
dc.subject.keywordPlusMETAL-COMPLEXES-
dc.subject.keywordPlusLIGANDS-
dc.subject.keywordPlusSALTS-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusDICARBOLLYLAMINO-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordAuthorMetallacarborane-
dc.subject.keywordAuthorCharge-compensated metal complexes-
dc.subject.keywordAuthorChromium-
dc.subject.keywordAuthorHydrogen bond-
dc.subject.keywordAuthorX-ray crystallography-
Files in This Item
There are no files associated with this item.
Appears in
Collections
Graduate School > Department of Advanced Materials Chemistry > 1. Journal Articles
Show simple item record

qrcode

Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.

Altmetrics

Total Views & Downloads

STATISTICS
Total View :8,352,071
Today View :5,094

RSS_1.0 RSS_2.0 ATOM_1.0

CONTACT US

(02841) 서울특별시 성북구 안암로 14502-3290-1114

COPYRIGHT © 2021 Korea University. All Rights Reserved.

Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.

BROWSE

English