Reversible Luminescence Vapochromism and Crystal-to-Amorphous-to-Crystal Transformations of Pseudopolymorphic Cu(I) Coordination Polymers
DC Field | Value | Language |
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dc.contributor.author | Kang, Gihaeng | - |
dc.contributor.author | Jeon, Youngeun | - |
dc.contributor.author | Lee, Kang Yeol | - |
dc.contributor.author | Kim, Jineun | - |
dc.contributor.author | Kim, Tae Ho | - |
dc.date.accessioned | 2021-09-04T10:52:00Z | - |
dc.date.available | 2021-09-04T10:52:00Z | - |
dc.date.created | 2021-06-10 | - |
dc.date.issued | 2015-11 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/91969 | - |
dc.description.abstract | Four solvent-responsive one-dimensional copper(I) coordination polymers (CPs), namely, {[Cu4I4L(MeCN)(2)]center dot CH2Cl2}(n) (1), {[Cu4I4L(MeCN)(2)]center dot CHCl3}(n) (2), {[Cu4I4L(MeCN)(2)]center dot 0.5p-xylene}(n) (3), and [Cu4I4L(MeCN)(2)](n) (4), were prepared by reaction of CuI with N,N'-bis[2-(cyclohexylthio)ethyl]pyromellitic diimide (L) via self-assembly under varying solvent conditions. CPs 1-4, which are pseudopolymorphic supramolecular isomers derived from solvent molecules, are composed of Cu4I4 cubane clusters. The ligands in CPs 1-3 adopted a synconformation, whereas in CP 4 they were observed in the anti-conformation. This occurred via syn to anti transitions upon heating, followed by exposure to MeCN vapor. In addition, a reversible anti to syn transition was achieved by agitating in mixed organic solvents. It was shown that ligand transition from the syn- to the anti-conformation occurred through crystal-to-amorphous-to-crystal transformations. Furthermore, CPs 1-3 exhibited reversible solvent exchange and crystal transformation by exposure to vapors from volatile organic compounds. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | METAL-ORGANIC FRAMEWORK | - |
dc.subject | CO2 ADSORPTION | - |
dc.subject | COMPLEXES | - |
dc.subject | EXCHANGE | - |
dc.title | Reversible Luminescence Vapochromism and Crystal-to-Amorphous-to-Crystal Transformations of Pseudopolymorphic Cu(I) Coordination Polymers | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Kang Yeol | - |
dc.identifier.doi | 10.1021/acs.cgd.5b01199 | - |
dc.identifier.scopusid | 2-s2.0-84946887368 | - |
dc.identifier.wosid | 000364356000003 | - |
dc.identifier.bibliographicCitation | CRYSTAL GROWTH & DESIGN, v.15, no.11, pp.5183 - 5187 | - |
dc.relation.isPartOf | CRYSTAL GROWTH & DESIGN | - |
dc.citation.title | CRYSTAL GROWTH & DESIGN | - |
dc.citation.volume | 15 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 5183 | - |
dc.citation.endPage | 5187 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORK | - |
dc.subject.keywordPlus | CO2 ADSORPTION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | EXCHANGE | - |
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