Concise Synthesis of Broussonone A
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jo, Hyeju | - |
dc.contributor.author | Choi, Minho | - |
dc.contributor.author | Viji, Mayavan | - |
dc.contributor.author | Lee, Young Hee | - |
dc.contributor.author | Kwak, Young-Shin | - |
dc.contributor.author | Lee, Kiho | - |
dc.contributor.author | Choi, Nam Song | - |
dc.contributor.author | Lee, Yeon-Ju | - |
dc.contributor.author | Lee, Heesoon | - |
dc.contributor.author | Hong, Jin Tae | - |
dc.contributor.author | Lee, Mi Kyeong | - |
dc.contributor.author | Jung, Jae-Kyung | - |
dc.date.accessioned | 2021-09-04T13:10:16Z | - |
dc.date.available | 2021-09-04T13:10:16Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2015-09 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/92650 | - |
dc.description.abstract | A concise and expeditious approach to the total synthesis of broussonone A, a p-quinol natural compound, has been developed. The key features of the synthesis include the Grubbs II catalyst mediated cross metathesis of two aromatic subunits, and a chemoselective oxidative dearomatizationin the presence of two phenol moieties. Especially, optimization associated with the CM reaction of ortho-alkoxystyrenes was also studied, which are known to be ineffective for Ru-catalyzed metathesis reactions under conventional reaction conditions because ortho-alkoxy group could coordinate to the ruthenium center, resulting in the potential complication of catalyst inhibition. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | MDPI AG | - |
dc.subject | OLEFIN CROSS METATHESIS | - |
dc.subject | ANTIINFLAMMATORY ACTIVITY | - |
dc.subject | LIPASE INHIBITORS | - |
dc.subject | IDENTIFICATION | - |
dc.subject | DERIVATIVES | - |
dc.subject | OXIDATION | - |
dc.subject | CATALYSTS | - |
dc.title | Concise Synthesis of Broussonone A | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kwak, Young-Shin | - |
dc.contributor.affiliatedAuthor | Lee, Kiho | - |
dc.identifier.doi | 10.3390/molecules200915966 | - |
dc.identifier.scopusid | 2-s2.0-84947968901 | - |
dc.identifier.wosid | 000362505300030 | - |
dc.identifier.bibliographicCitation | MOLECULES, v.20, no.9, pp.15966 - 15975 | - |
dc.relation.isPartOf | MOLECULES | - |
dc.citation.title | MOLECULES | - |
dc.citation.volume | 20 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 15966 | - |
dc.citation.endPage | 15975 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Biochemistry & Molecular Biology | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Biochemistry & Molecular Biology | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | OLEFIN CROSS METATHESIS | - |
dc.subject.keywordPlus | ANTIINFLAMMATORY ACTIVITY | - |
dc.subject.keywordPlus | LIPASE INHIBITORS | - |
dc.subject.keywordPlus | IDENTIFICATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordAuthor | broussonone A | - |
dc.subject.keywordAuthor | cross metathesis | - |
dc.subject.keywordAuthor | Grubbs catalyst | - |
dc.subject.keywordAuthor | oxidative dearomatization | - |
dc.subject.keywordAuthor | PIFA | - |
dc.subject.keywordAuthor | total synthesis | - |
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