Effect of a Pt-ZrO2 protection layer on the performance and morphology of Pd-Au alloy membrane during H2S exposure
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Sung-Wook | - |
dc.contributor.author | Oh, Duck-Kyu | - |
dc.contributor.author | Park, Jin-Woo | - |
dc.contributor.author | Lee, Chun-Boo | - |
dc.contributor.author | Lee, Dong-Wook | - |
dc.contributor.author | Park, Jong-Soo | - |
dc.contributor.author | Kim, Sung-Hyun | - |
dc.contributor.author | Hwang, Kyung-Ran | - |
dc.date.accessioned | 2021-09-04T13:21:46Z | - |
dc.date.available | 2021-09-04T13:21:46Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2015-08-25 | - |
dc.identifier.issn | 0925-8388 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/92731 | - |
dc.description.abstract | We prepared a disc-type Pd-Au alloy membrane, on which a Pt-ZrO2 protection layer was deposited to protect the hydrogen membrane from H2S poisoning. The effect of the protection layer on the performance and morphology of the Pd-Au alloy membrane during H2S exposure was investigated. The hydrogen flux did not decrease significantly in the presence of the protection layer, which covered the surface of the membrane. When the membrane with the protection layer was exposed to a mixture of H2S, the hydrogen flux decreased to 35% of the original value, which is half of the decrease observed with the bare Pd-Au membrane. The hydrogen flux of the poisoned membrane was almost completely recovered after changing back to pure H-2 gas. Under harsh conditions, the membrane with the protection layer was found to retain the hydrogen flux and selectivity, while the selectivity of the bare membrane decreased to zero, indicating that it was disintegrated. This means that the Pt-ZrO2 layer prevents direct contact between Pd and H2S, thus protecting the Pd membrane from poisoning. (C) 2015 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | HYDROGEN | - |
dc.subject | TECHNOLOGY | - |
dc.subject | COMBUSTION | - |
dc.subject | METHANE | - |
dc.title | Effect of a Pt-ZrO2 protection layer on the performance and morphology of Pd-Au alloy membrane during H2S exposure | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Sung-Hyun | - |
dc.identifier.doi | 10.1016/j.jallcom.2015.03.210 | - |
dc.identifier.scopusid | 2-s2.0-84929459555 | - |
dc.identifier.wosid | 000354195900035 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ALLOYS AND COMPOUNDS, v.641, pp.210 - 215 | - |
dc.relation.isPartOf | JOURNAL OF ALLOYS AND COMPOUNDS | - |
dc.citation.title | JOURNAL OF ALLOYS AND COMPOUNDS | - |
dc.citation.volume | 641 | - |
dc.citation.startPage | 210 | - |
dc.citation.endPage | 215 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Metallurgy & Metallurgical Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Metallurgy & Metallurgical Engineering | - |
dc.subject.keywordPlus | HYDROGEN | - |
dc.subject.keywordPlus | TECHNOLOGY | - |
dc.subject.keywordPlus | COMBUSTION | - |
dc.subject.keywordPlus | METHANE | - |
dc.subject.keywordAuthor | Pd alloy membrane | - |
dc.subject.keywordAuthor | Hydrogen | - |
dc.subject.keywordAuthor | Hydrogen sulfide | - |
dc.subject.keywordAuthor | Pt-ZrO2 | - |
dc.subject.keywordAuthor | Protection layer | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.