Kilogram-Scale Synthesis of Pd-Loaded Quintuple-Shelled Co3O4 Microreactors and Their Application to Ultrasensitive and Ultraselective Detection of Methylbenzenes
DC Field | Value | Language |
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dc.contributor.author | Yoon, Ji-Wook | - |
dc.contributor.author | Hong, Young Jun | - |
dc.contributor.author | Park, Gi Dae | - |
dc.contributor.author | Hwang, Su-Jin | - |
dc.contributor.author | Abdel-Hady, Faissal | - |
dc.contributor.author | Wazzan, AbdulAziz A. | - |
dc.contributor.author | Kang, Yun Chan | - |
dc.contributor.author | Lee, Jong-Heun | - |
dc.date.accessioned | 2021-09-04T17:13:34Z | - |
dc.date.available | 2021-09-04T17:13:34Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2015-04-15 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/93836 | - |
dc.description.abstract | We report the kilogram-scale, simple, and cost-effective synthesis of Pd-loaded quintuple-shelled Co3O4 microreactors by spray drying of aqueous droplets containing cobalt nitrate, palladium nitrate, citric acid, and ethylene glycol and subsequent heat treatment. Highly viscous gel spheres containing Co and Pd salts were successfully converted into multi thin-shelled Co3O4 reactors uniformly loaded with Pd catalysts by the sequential combustion of carbon and decomposition of the metal salts from the outer to the inner regions during one-step heat treatment. The responses (resistance ratio) of the Pd-loaded quintuple-shelled Co3O4 microreactors to 5 ppm toluene and p-xylene were 30.8 and 64.2, respectively, and the selectivity values to toluene and p-xylene against ethanol interference (response ratio) were 14.5 and 30.1, respectively. The unprecedented high response and selectivity were attributed to the effective dissociation of less reactive methylbenzenes into more active smaller species assisted both by catalytic Co3O4 and Pd during the prolonged retention within the microreactors. Kilogram-scale preparation of noble metal-loaded multishelled microreactors and their unique gas-sensing characteristics based on a novel microreactor concept can pave a new way to design of high-performance gas sensors for practical applications. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | ETHANOL SENSING PROPERTIES | - |
dc.subject | LITHIUM-ION BATTERIES | - |
dc.subject | X-RAY PHOTOELECTRON | - |
dc.subject | YOLK-SHELL | - |
dc.subject | GAS SENSORS | - |
dc.subject | FACILE SYNTHESIS | - |
dc.subject | RECENT PROGRESS | - |
dc.subject | NANOSTRUCTURES | - |
dc.subject | NANOREACTORS | - |
dc.subject | NANORODS | - |
dc.title | Kilogram-Scale Synthesis of Pd-Loaded Quintuple-Shelled Co3O4 Microreactors and Their Application to Ultrasensitive and Ultraselective Detection of Methylbenzenes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kang, Yun Chan | - |
dc.contributor.affiliatedAuthor | Lee, Jong-Heun | - |
dc.identifier.doi | 10.1021/acsami.5b00706 | - |
dc.identifier.scopusid | 2-s2.0-84927950534 | - |
dc.identifier.wosid | 000353177000035 | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.7, no.14, pp.7717 - 7723 | - |
dc.relation.isPartOf | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 7 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 7717 | - |
dc.citation.endPage | 7723 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | ETHANOL SENSING PROPERTIES | - |
dc.subject.keywordPlus | LITHIUM-ION BATTERIES | - |
dc.subject.keywordPlus | X-RAY PHOTOELECTRON | - |
dc.subject.keywordPlus | YOLK-SHELL | - |
dc.subject.keywordPlus | GAS SENSORS | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | RECENT PROGRESS | - |
dc.subject.keywordPlus | NANOSTRUCTURES | - |
dc.subject.keywordPlus | NANOREACTORS | - |
dc.subject.keywordPlus | NANORODS | - |
dc.subject.keywordAuthor | gas sensor | - |
dc.subject.keywordAuthor | Pd-loaded Co3O4 | - |
dc.subject.keywordAuthor | yolk-shell microreactor | - |
dc.subject.keywordAuthor | kilogram-scale preparation | - |
dc.subject.keywordAuthor | selectivity | - |
dc.subject.keywordAuthor | methylbenzenes | - |
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