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Asymmetric Pauson-Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis

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dc.contributor.authorFurusawa, Takuma-
dc.contributor.authorMorimoto, Tsumoru-
dc.contributor.authorIkeda, Keiichi-
dc.contributor.authorTanimoto, Hiroki-
dc.contributor.authorNishiyama, Yasuhiro-
dc.contributor.authorKakiuchi, Kiyomi-
dc.contributor.authorJeong, Nakcheol-
dc.date.accessioned2021-09-04T19:18:33Z-
dc.date.available2021-09-04T19:18:33Z-
dc.date.created2021-06-15-
dc.date.issued2015-02-04-
dc.identifier.issn0040-4020-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/94419-
dc.description.abstractA dual neutral-cationic rhodium(I)-catalyzed Pauson-Khand-type reaction using formaldehyde as a carbonyl source is described. The simultaneous use of neutral rhodium(I) and cationic rhodium(l) complexes is required for efficient cooperative catalysis, which involves the neutral rhodium(l)-catalyzed decarbonylation of formaldehyde and the cationic rhodium(I)-catalyzed cyclocarbonylation of 1,6-enynes using the resulting carbonyl moiety. (C) 2014 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectC BOND FORMATION-
dc.subjectCYCLIZATION-
dc.subjectCYCLOCARBONYLATION-
dc.subjectENYNES-
dc.subjectDECARBONYLATION-
dc.subjectALDEHYDES-
dc.subjectHYDROGEN-
dc.subjectCAPTURE-
dc.titleAsymmetric Pauson-Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis-
dc.typeArticle-
dc.contributor.affiliatedAuthorJeong, Nakcheol-
dc.identifier.doi10.1016/j.tet.2014.12.038-
dc.identifier.scopusid2-s2.0-84920746902-
dc.identifier.wosid000349194000016-
dc.identifier.bibliographicCitationTETRAHEDRON, v.71, no.5, pp.875 - 881-
dc.relation.isPartOfTETRAHEDRON-
dc.citation.titleTETRAHEDRON-
dc.citation.volume71-
dc.citation.number5-
dc.citation.startPage875-
dc.citation.endPage881-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusC BOND FORMATION-
dc.subject.keywordPlusCYCLIZATION-
dc.subject.keywordPlusCYCLOCARBONYLATION-
dc.subject.keywordPlusENYNES-
dc.subject.keywordPlusDECARBONYLATION-
dc.subject.keywordPlusALDEHYDES-
dc.subject.keywordPlusHYDROGEN-
dc.subject.keywordPlusCAPTURE-
dc.subject.keywordAuthorAsymmetric Pauson-Khand reaction-
dc.subject.keywordAuthorDecarbonylation-
dc.subject.keywordAuthorFormaldehyde-
dc.subject.keywordAuthorEnyne-
dc.subject.keywordAuthorDual catalysis-
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