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Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline

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dc.contributor.authorPark, Sun Hee-
dc.contributor.authorPark, Yumi-
dc.contributor.authorHan, Jeong Sik-
dc.contributor.authorJeong, Byung Hun-
dc.contributor.authorHan, Hogyu-
dc.contributor.authorKim, Sung Hyun-
dc.date.accessioned2021-09-04T20:22:21Z-
dc.date.available2021-09-04T20:22:21Z-
dc.date.created2021-06-15-
dc.date.issued2015-01-
dc.identifier.issn0887-0624-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/94732-
dc.description.abstractWe investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.subjectSINK JET FUELS-
dc.subjectOIL (RCO/LCO)-DERIVED STABILIZERS-
dc.subjectSIMILAR HYDROCARBON MIXTURES-
dc.subjectHIGH-TEMPERATURE STABILIZERS-
dc.subjectSOLID DEPOSITS-
dc.subjectN-DODECANE-
dc.subjectMODEL-
dc.subjectJP-8-
dc.subjectFLUOROTYROSINES-
dc.subjectDECOMPOSITION-
dc.titleMechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline-
dc.typeArticle-
dc.contributor.affiliatedAuthorHan, Hogyu-
dc.contributor.affiliatedAuthorKim, Sung Hyun-
dc.identifier.doi10.1021/ef5016445-
dc.identifier.scopusid2-s2.0-84921422831-
dc.identifier.wosid000348094100003-
dc.identifier.bibliographicCitationENERGY & FUELS, v.29, no.1, pp.16 - 20-
dc.relation.isPartOfENERGY & FUELS-
dc.citation.titleENERGY & FUELS-
dc.citation.volume29-
dc.citation.number1-
dc.citation.startPage16-
dc.citation.endPage20-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaEnergy & Fuels-
dc.relation.journalResearchAreaEngineering-
dc.relation.journalWebOfScienceCategoryEnergy & Fuels-
dc.relation.journalWebOfScienceCategoryEngineering, Chemical-
dc.subject.keywordPlusSINK JET FUELS-
dc.subject.keywordPlusOIL (RCO/LCO)-DERIVED STABILIZERS-
dc.subject.keywordPlusSIMILAR HYDROCARBON MIXTURES-
dc.subject.keywordPlusHIGH-TEMPERATURE STABILIZERS-
dc.subject.keywordPlusSOLID DEPOSITS-
dc.subject.keywordPlusN-DODECANE-
dc.subject.keywordPlusMODEL-
dc.subject.keywordPlusJP-8-
dc.subject.keywordPlusFLUOROTYROSINES-
dc.subject.keywordPlusDECOMPOSITION-
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