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Synthesis, luminescence properties, and growth mechanisms of YF3:Yb3+/Er3+ nanoplates

Authors
Murali, G.Lee, Byeong HoonMishra, R. K.Lee, Jae MyeongNam, Sang-HwanSuh, Yung DougLim, Dong-KwonLee, Joong HeeLee, Seung Hee
Issue Date
2015
Publisher
ROYAL SOC CHEMISTRY
Citation
JOURNAL OF MATERIALS CHEMISTRY C, v.3, no.39, pp.10107 - 10113
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF MATERIALS CHEMISTRY C
Volume
3
Number
39
Start Page
10107
End Page
10113
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/96347
DOI
10.1039/c5tc02034d
ISSN
2050-7526
Abstract
Anisotropically structured upconversion nanocrystals capable of exhibiting bright upconversion emission properties are a promising new class of high performance optical materials. In this study, we investigate a facile synthetic method for the new nanoplate structure of YF3:Yb3+/Er3+ with enhanced luminescence intensity. The shape of YF3:Yb3+/Er3+ nanocrystals can be controlled by changing the synthesis conditions of the NaOH concentration, reaction time, and surfactant. The concentration of NaOH determines the final structure of YF3:Yb3+/Er3+. By increasing the NaOH concentration from 0.25 mmol to 2.5 mmol, YF3:Yb3+/Er3+ nanoplates transform into NaYF4:Yb3+/Er3+ nanoparticles; in the absence of NaOH, the nanoplate structure of YF3:Yb3+/Er3+ changes to particles. The YF3:Yb3+/Er3+ nanoplates show luminescence efficiency much greater than that of the spherical YF3:Yb3+/Er3+ nanocrystals.
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