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Ferromagnetic Ordering in Superatomic Solids

Authors
Lee, Chul-HoLiu, LianBejger, ChristopherTurkiewicz, AriGoko, TatsuoArguello, Carlos J.Frandsen, Benjamin A.Cheung, Sky C.Medina, TeresaMunsie, Timothy J. S.D'Ortenzio, RobertLuke, Graeme M.Besara, TigletLalancette, Roger A.Siegrist, TheoStephens, Peter W.Crowther, Andrew C.Brus, Louis E.Matsuo, YutakaNakamura, EiichiUemura, Yasutomo J.Kim, PhilipNuckolls, ColinSteigerwald, Michael L.Roy, Xavier
Issue Date
3-12월-2014
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.136, no.48, pp.16926 - 16931
Indexed
SCIE
SCOPUS
Journal Title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume
136
Number
48
Start Page
16926
End Page
16931
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/96535
DOI
10.1021/ja5098622
ISSN
0002-7863
Abstract
In order to realize significant benefits from the assembly of solid-state materials from molecular cluster superatomic building blocks, several criteria must be met. Reproducible syntheses must reliably produce macroscopic amounts of pure material; the cluster-assembled solids must show properties that are more than simply averages of those of the constituent subunits; and rational changes to the chemical structures of the subunits must result in predictable changes in the collective properties of the solid. In this report we show that we can meet these requirements. Using a combination of magnetometry and muon spin relaxation measurements, we demonstrate that crystallographically defined superatomic solids assembled from molecular nickel telluride clusters and fullerenes undergo a ferromagnetic phase transition at low temperatures. Moreover, we show that when we modify the constituent superatoms, the cooperative magnetic properties change in predictable ways.
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