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Palladium-Catalyzed Decarboxylative Trifluoroethylation of Aryl Alkynyl Carboxylic Acids
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Hwang, Jinil | - |
| dc.contributor.author | Park, Kyungho | - |
| dc.contributor.author | Choe, Juseok | - |
| dc.contributor.author | Min, Hongkeun | - |
| dc.contributor.author | Song, Kwang Ho | - |
| dc.contributor.author | Lee, Sunwoo | - |
| dc.date.accessioned | 2021-09-05T09:43:17Z | - |
| dc.date.available | 2021-09-05T09:43:17Z | - |
| dc.date.created | 2021-06-15 | - |
| dc.date.issued | 2014-04-04 | - |
| dc.identifier.issn | 0022-3263 | - |
| dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/98781 | - |
| dc.description.abstract | A trifluoroethylation of alkynes through a palladium-catalyzed decarboxylative coupling reaction was developed. When alkynyl carboxylic acids and ICH2CF3 were allowed to react with [Pd(eta(3)-allyl)Cl](2)/XantPhos and Cs2CO3 in N,N-dimethylformamide (DMF) at 80 degrees C for 1 h, the desired products were formed in good yields. This catalytic system showed high functional group tolerance. | - |
| dc.language | English | - |
| dc.language.iso | en | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.subject | TERMINAL ALKYNES | - |
| dc.subject | ELECTROPHILIC TRIFLUOROMETHYLATION | - |
| dc.subject | OXIDATIVE TRIFLUOROMETHYLATION | - |
| dc.subject | MEDIATED FLUORINATION | - |
| dc.subject | UNACTIVATED ALKENES | - |
| dc.subject | COUPLING REACTIONS | - |
| dc.subject | HALIDES | - |
| dc.subject | AMINOFLUORINATION | - |
| dc.subject | STRATEGY | - |
| dc.subject | CARBON | - |
| dc.title | Palladium-Catalyzed Decarboxylative Trifluoroethylation of Aryl Alkynyl Carboxylic Acids | - |
| dc.type | Article | - |
| dc.contributor.affiliatedAuthor | Song, Kwang Ho | - |
| dc.identifier.doi | 10.1021/jo5003032 | - |
| dc.identifier.scopusid | 2-s2.0-84898060263 | - |
| dc.identifier.wosid | 000334016500049 | - |
| dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.79, no.7, pp.3267 - 3271 | - |
| dc.relation.isPartOf | JOURNAL OF ORGANIC CHEMISTRY | - |
| dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
| dc.citation.volume | 79 | - |
| dc.citation.number | 7 | - |
| dc.citation.startPage | 3267 | - |
| dc.citation.endPage | 3271 | - |
| dc.type.rims | ART | - |
| dc.type.docType | Article | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | TERMINAL ALKYNES | - |
| dc.subject.keywordPlus | ELECTROPHILIC TRIFLUOROMETHYLATION | - |
| dc.subject.keywordPlus | OXIDATIVE TRIFLUOROMETHYLATION | - |
| dc.subject.keywordPlus | MEDIATED FLUORINATION | - |
| dc.subject.keywordPlus | UNACTIVATED ALKENES | - |
| dc.subject.keywordPlus | COUPLING REACTIONS | - |
| dc.subject.keywordPlus | HALIDES | - |
| dc.subject.keywordPlus | AMINOFLUORINATION | - |
| dc.subject.keywordPlus | STRATEGY | - |
| dc.subject.keywordPlus | CARBON | - |
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