Reversible Structural Flexibility and Sensing Properties of a Zn(II) Metal-Organic Framework: Phase Transformation between Interpenetrating 3D Net and 2D Sheet
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yeonga | - |
dc.contributor.author | Song, Jeong Hwa | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.contributor.author | Phang, Won Ju | - |
dc.contributor.author | Lim, Kwang Soo | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2021-09-05T10:04:42Z | - |
dc.date.available | 2021-09-05T10:04:42Z | - |
dc.date.created | 2021-06-15 | - |
dc.date.issued | 2014-04 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/98851 | - |
dc.description.abstract | A three-dimensional Zn(II) framework, [Zn4O(L)(3)(DMF)(2)]center dot 0.5DMF center dot H2O (1; H2L = 3,3'-dimethoxybiphenyl-4,4'-dicarboxylic acid) was prepared under a solvothermal reaction in DMF. The structure reveals that the 3-fold interpenetration is stabilized in the framework with a distinct secondary building unit of the formula [Zn4O(R-CO2)(6)(DMF)(2)], slightly different from that of MOF-5. Phase transformations in 1 occur reversibly via two pathways of solvent exchange/resolvation and activation/resolvation, which is indicative of the presence of extensive structural flexibility. Nitrobenzene among tested solvents is selectively detected by 1, and the sensing event was operating repeatedly. The three-dimensional framework of 1 with 3-fold interpenetration is uniquely converted to the two-dimensional Cu phase with no interpenetration, reflecting a drastic dimensionality variation. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | COORDINATION POLYMER | - |
dc.subject | NITROAROMATIC EXPLOSIVES | - |
dc.subject | SINGLE-CRYSTAL | - |
dc.subject | NETWORKS | - |
dc.subject | LUMINESCENCE | - |
dc.subject | NITROBENZENE | - |
dc.subject | TEMPERATURE | - |
dc.subject | TOPOLOGIES | - |
dc.subject | CLUSTERS | - |
dc.subject | MOF | - |
dc.title | Reversible Structural Flexibility and Sensing Properties of a Zn(II) Metal-Organic Framework: Phase Transformation between Interpenetrating 3D Net and 2D Sheet | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1021/cg500052v | - |
dc.identifier.scopusid | 2-s2.0-84897539371 | - |
dc.identifier.wosid | 000333948000049 | - |
dc.identifier.bibliographicCitation | CRYSTAL GROWTH & DESIGN, v.14, no.4, pp.1933 - 1937 | - |
dc.relation.isPartOf | CRYSTAL GROWTH & DESIGN | - |
dc.citation.title | CRYSTAL GROWTH & DESIGN | - |
dc.citation.volume | 14 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 1933 | - |
dc.citation.endPage | 1937 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | COORDINATION POLYMER | - |
dc.subject.keywordPlus | NITROAROMATIC EXPLOSIVES | - |
dc.subject.keywordPlus | SINGLE-CRYSTAL | - |
dc.subject.keywordPlus | NETWORKS | - |
dc.subject.keywordPlus | LUMINESCENCE | - |
dc.subject.keywordPlus | NITROBENZENE | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | TOPOLOGIES | - |
dc.subject.keywordPlus | CLUSTERS | - |
dc.subject.keywordPlus | MOF | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.