Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet

Choi, Seok Woo; Kwak, Hyun Young; Yoon, Jung Hee; Kim, Hyoung Chan; Koh, Eui Kwan; Hong, Chang Seop

doi:10.1021/ic801699p

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Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet

Choi, Seok Woo;
Kwak, Hyun Young;
Yoon, Jung Hee;
Kim, Hyoung Chan;
Koh, Eui Kwan;
... Hong, Chang Seop

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82

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84

초록

Assembling [W(CN)(6)(bpy)](-) and magnetic anisotropic Mn Schiff bases produced two Mn-III(3d)-W-V(5d) bimetallic chains. Modulation of the types and degrees of interchain pi-pi interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.

키워드

CRYSTAL-STRUCTURES; COMPLEXES; BEHAVIOR; AZIDE; NANOWIRES; PRECURSOR; SERIES; UNITS

제목: Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet

저자: Choi, Seok Woo; Kwak, Hyun Young; Yoon, Jung Hee; Kim, Hyoung Chan; Koh, Eui Kwan; Hong, Chang Seop

DOI: 10.1021/ic801699p

발행일: 2008-11-17

유형: Article

저널명: Inorganic Chemistry

권: 47

호: 22

페이지: 10214 ~ 10216

언어: ENG

출판사: AMER CHEMICAL SOC

발행국가: 미국

분량: 3 페이지

ISSN: E 1520-510X
P 0020-1669