An extraordinary cylinder-to-cylinder transition in the aqueous assemblies of fluorescently labeled rod-coil amphiphiles

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초록

We report an unprecedented cylinder-to-cylinder transformation in the self-assemblies of pyrene-labeled rod-coil molecules in water. The extraordinary morphological transformation can be monitored by a fluorescence variation from exciplex to excimer emissions, suggesting the rod-packing transition from antiparallel to interdigitated arrangements as a function of PEO coil length.

키워드

BLOCK-COPOLYMERSDIBLOCK COPOLYMERSMULTIPLE MORPHOLOGIESCYLINDRICAL MICELLESMOLECULESLIQUID
제목
An extraordinary cylinder-to-cylinder transition in the aqueous assemblies of fluorescently labeled rod-coil amphiphiles
저자
Han, Kyung-HeeLee, EunjiKim, Jong SeungCho, Byoung-Ki
DOI
10.1021/ja806128e
발행일
2008-10-22
유형
Article
저널명
Journal of the American Chemical Society
130
42
페이지
13858 ~ 13859