Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane

Park, Jinhyung; Kwon, Young Bum; Yang, Kyungmo; Rhee, Hakjune; Yoon, Cheol Min

doi:10.1055/s-0029-1218612

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Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane

Park, Jinhyung;
Kwon, Young Bum;
Yang, Kyungmo;
Rhee, Hakjune;
Yoon, Cheol Min

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WEB OF SCIENCE

8

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SCOPUS

9

초록

Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPh3)(4) or Pd(dba)(2) as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-dienes in good to high yields.

키워드

Baylis-Hillman acetates; allyltributylstannane; bis-pi-allylpalladium; 1,5-diene; allylation; ACTIVATED DOUBLE-BONDS; NECIC ACID SYNTHONS; STEREOSELECTIVE-SYNTHESIS; (Z)-TRISUBSTITUTED ALKENES; CHEMOSELECTIVE ALLYLATION; ADDUCTS; ALDEHYDES; ELECTROPHILES; ISOMERIZATION; REACTIVITY

제목: Efficient Palladium-Catalyzed Coupling of Baylis-Hillman Acetates with an Allylstannane

저자: Park, Jinhyung; Kwon, Young Bum; Yang, Kyungmo; Rhee, Hakjune; Yoon, Cheol Min

DOI: 10.1055/s-0029-1218612

발행일: 2010-02

유형: Article

저널명: Synthesis

호: 4

페이지: 661 ~ 665