A three-dimensional pi-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units

  • Jin, Guo Fan
  • Hwang, Jo-Hyun
  • Lee, Jong-Dae
  • Wee, Kyung-Ryang
  • Suh, Il-Hwan
  • 외 1명
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초록

Electron accepting capability is greatly improved for B-phenylated tri-phenyl-o-carborane (1) through a favorable electronic interaction between the two adjoining phenyl-pi(star) and cage carbon-sigma(star) orbitals.

키워드

ICOSAHEDRAL CARBORANESCRYSTAL-STRUCTUREEMISSIONDISTANCEATOMNH2
제목
A three-dimensional pi-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units
저자
Jin, Guo FanHwang, Jo-HyunLee, Jong-DaeWee, Kyung-RyangSuh, Il-HwanKang, Sang Ook
DOI
10.1039/c3cc45313h
발행일
2013
유형
Article
저널명
Chemical Communications
49
82
페이지
9398 ~ 9400