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초록
Desulfurization of a variety of thiiranes to alkenes occurs chemoselectively in high yields upon treatment with MoCl5/Zn system under mild conditions. The new methodology demonstrates high functional group tolerance toward chloro, bromo, fluoro, methoxy, ester, ether and keto groups.
키워드
Desulfurization; thiirane; alkene; molybdenum(V) chloride; zinc; SELECTIVE DEBROMINATION; VIC-DIBROMIDES; ATOM-TRANSFER; DEOXYGENATION; SULFOXIDES; TUNGSTEN(VI); ALKENES
- 제목
- Mild and efficient desulfurization of thiiranes with MoCl5/Zn system
- 저자
- Yoo, Byung Woo; Lee, Yeong Jin; Shin, Jeong Won
- 발행일
- 2022-03
- 유형
- Article
- 권
- 43
- 호
- 2
- 페이지
- 124 ~ 131