A Rationally Designed Fluorescence Turn-On Probe for the Gold(III) Ion

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초록

A latent fluorophore (1) was rationally designed to give rise to strong fluorescence through a selective gold ion-mediated hydroarylation reaction by a catalytic amount of the gold(III) ion. It is a highly selective and sensitive fluorescence turn-on probe for gold(III) ions and is operative even in protic solvents.

키워드

FRIEDEL-CRAFTS ALKENYLATIONLATENT FLUOROPHOREGOLD CATALYSISALKYNESHYDROARYLATIONCOMPLEXESEFFICIENTLIQUIDARENESTOXINS
제목
A Rationally Designed Fluorescence Turn-On Probe for the Gold(III) Ion
저자
Do, Jung HoKim, Ha NaYoon, JuyoungKim, Jong SeungKim, Hae-Jo
DOI
10.1021/ol902860f
발행일
2010-03-05
유형
Article
저널명
Organic Letters
12
5
페이지
932 ~ 934