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Calix[2]triazole[2]arenes; A Class of Hybrid Heterocalixarenes
- Cho, Jihee;
- Lee, Seokwoo;
- Hwang, Soonho;
- Kim, Sang Hoon;
- Kim, Jong Seung;
- 외 1명
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13초록
A series of calix[2]triazole[2]arenes, which are members of the heterocalixarene family, were generated by copper(I)-catalyzed Huisgen reaction in a one-pot synthesis. Their various conformational structures and physical properties were characterized by a computational, NMR spectroscopic, and X-ray structural investigation. Among six conformations, the 1,2-alternate conformation was found to be the most stable due to two intramolecular hydrogen bonds between the phenolic hydroxyl group and the triazole nitrogen atom.
키워드
Supramolecular chemistry; Calixarenes; Click chemistry; Conformation analysis; Structure elucidation; SELECTIVE RECOGNITION; FLUORESCENCE SENSOR; TRIAZOLE; CONJUGATE; MACROCYCLE; ZN2+; CYCLOADDITIONS; PYROPHOSPHATE; CONSTRUCTION; SUBSTITUENTS
- 제목
- Calix[2]triazole[2]arenes; A Class of Hybrid Heterocalixarenes
- 저자
- Cho, Jihee; Lee, Seokwoo; Hwang, Soonho; Kim, Sang Hoon; Kim, Jong Seung; Kim, Sanghee
- 발행일
- 2013-07
- 유형
- Article
- 권
- 2013
- 호
- 21
- 페이지
- 4614 ~ 4623