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Ferrocene-Appended Aryl Triazole for Electrochemical Recognition of Phosphate Ions
- Cao, Qian-Yong;
- Pradhan, Tuhin;
- Kim, Sungtae;
- Kim, Jong Seung
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91초록
A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C-H center dot center dot center dot O) with a tetrahedral anion, which Is supported by density functional theory based theoretical calculation and H-1 NMR titration results.
키워드
MOLECULAR RECOGNITION; MACROCYCLIC RECEPTOR; ANION RECOGNITION; CLICK CHEMISTRY; METAL-CATIONS; HYDROGEN-BOND; PYROPHOSPHATE; BINDING; DENDRIMERS; CHEMOSENSORS
- 제목
- Ferrocene-Appended Aryl Triazole for Electrochemical Recognition of Phosphate Ions
- 저자
- Cao, Qian-Yong; Pradhan, Tuhin; Kim, Sungtae; Kim, Jong Seung
- 발행일
- 2011-08-19
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 13
- 호
- 16
- 페이지
- 4386 ~ 4389