High yield synthesis of catalytically active five-fold twinned Pt nanorods from a surfactant-ligated precursor

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초록

The CO-assisted thermal decomposition of a new, surfactant-ligated Pt precursor, [Pt(acac)(NHR)](n) (n = 2, 3; R = C18H37), gives structurally uniform five-fold twinned Pt nanorods. The Pt nanorods, mostly covered by {100} facets, exhibit much enhanced electrocatalytic activity over {100} faceted Pt nanocubes, indicating the superior catalytic performance due to the presence of the reactive twinning interface.

키워드

SHAPE-CONTROLLED SYNTHESIS; HIGH-INDEX FACETS; PLATINUM NANOCRYSTALS; METAL NANOCRYSTALS; NANOPARTICLES; NANOWIRES; GROWTH; GOLD; SIZE; PALLADIUM
제목
High yield synthesis of catalytically active five-fold twinned Pt nanorods from a surfactant-ligated precursor
저자
Yoon, Jisun; Nguyen Tien Khi; Kim, Heonjo; Kim, Byeongyoon; Baik, Hionsuck; Back, Seunghoon; Lee, Sangmin; Lee, Sang-Won; Kwon, Seong Jung; Lee, Kwangyeol
DOI
10.1039/c2cc36905b
발행일
2013
유형
Article
저널명
Chemical Communications
권
49
호
6
페이지
573 ~ 575