Cyanide-bridged (WMnIII)-Mn-V single-chain magnet based on an octacoordinate [W(CN)(6)(phen)](-) anion

Lee, JinWuk; Lim, KwangSoo; Yoon, JungHee; Ryu, DaeWon; Koo, BongHo; Koh, EuiKwan; Hong, ChangSeop

doi:10.1007/s11426-012-4539-4

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Cyanide-bridged (WMnIII)-Mn-V single-chain magnet based on an octacoordinate [W(CN)(6)(phen)](-) anion

Lee, JinWuk;
Lim, KwangSoo;
Yoon, JungHee;
Ryu, DaeWon;
Koo, BongHo;
... Hong, ChangSeop;
외 1명

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초록

Reaction of unique [W(CN)(6)(phen)(-) with a magnetically anisotropic Mn Schiff base yielded a W-V(5d)-Mn-III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

키워드

tungsten; manganese; cyanide; crystal structure; single-chain magnet; CRYSTAL-STRUCTURES; METAL-IONS; MAGNETIZATION; RELAXATION; ANISOTROPY; EXCHANGE; BEHAVIOR; SYSTEMS; DESIGN; UNITS

제목: Cyanide-bridged (WMnIII)-Mn-V single-chain magnet based on an octacoordinate [W(CN)(6)(phen)](-) anion

저자: Lee, JinWuk; Lim, KwangSoo; Yoon, JungHee; Ryu, DaeWon; Koo, BongHo; Koh, EuiKwan; Hong, ChangSeop

DOI: 10.1007/s11426-012-4539-4

발행일: 2012-06

유형: Article

저널명: Science China Chemistry

권: 55

호: 6

페이지: 1012 ~ 1017