Hg2+-Induced hydrolysis-based selective fluorescent chemodosimeter

  • Kim, Ja Hyung
  • Kim, Hyun Jung
  • Bae, Chang Wan
  • Park, Jun Won
  • Lee, Joung Hae
  • ... Kim, Jong Seung
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초록

A new chemodosimeter-based approach to the detection of Hg(II) ions is described, involving the analyte-induced fluorescence enhancement of iminopyrene derivatives. The chemical and photo-physical properties of the chemodosimetric irreversible reaction between 1 and the Hg(II) ion were studied in a solution of CH3CN/H2O using H-1-NMR, UV/Vis, and fluorescence spectroscopies. Among the iminopyrenes 1-3, compound 1 shows a selective change in UV/Vis absorption, fluorescence emission, and color towards the Hg(II) cation over other cations in CH3CN:H2O (9:1).

키워드

Mercuric ioniminepyrenehydrolysischemodosimeterSCHIFF-BASESMERCURYCOBALT(II)COMPLEXESHG(II)HG2+RECOGNITIONCHEMOSENSORNICKEL(II)OXIDATION
제목
Hg2+-Induced hydrolysis-based selective fluorescent chemodosimeter
저자
Kim, Ja HyungKim, Hyun JungBae, Chang WanPark, Jun WonLee, Joung HaeKim, Jong Seung
DOI
10.3998/ark.5550190.0011.713
발행일
2010
유형
Article
저널명
Arkivoc
페이지
170 ~ 178