Synthesis of sterically-hindered 1,7-dicarba-closo-dodecarborane thiourea analogs

Choi, Seunghyun; Byun, Youngjoo

doi:10.1016/j.jorganchem.2013.03.003

상세 보기

Synthesis of sterically-hindered 1,7-dicarba-closo-dodecarborane thiourea analogs

Choi, Seunghyun;
Byun, Youngjoo

Citations

WEB OF SCIENCE

9

Citations

SCOPUS

8

초록

We herein report the first successful synthesis of 1-thioisocyanato-1,7-dicarba-closo-dodecarborane, which afforded novel lipophilic thiourea analogs by reacting with weak and bulky nucleophilic amines including 1-adamantylamine, and m-carboranylamine, aniline, and 2-aminopyridine. Newly synthesized thiourea analogs were fully characterized by NMR, ESI-MS, and FTIR. (C) 2013 Elsevier B.V. All rights reserved.

키워드

Carborane; Isothiocyanate; Thiourea; Conjugation; CARBORANE; BORON; PHARMACOPHORES

제목: Synthesis of sterically-hindered 1,7-dicarba-closo-dodecarborane thiourea analogs

저자: Choi, Seunghyun; Byun, Youngjoo

DOI: 10.1016/j.jorganchem.2013.03.003

발행일: 2013-06-01

유형: Article

저널명: Journal of Organometallic Chemistry

권: 733

페이지: 49 ~ 52