High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer

  • Heo, Jin Hyuck; 
  • Jang, Min Hyuk; 
  • Lee, Min Ho; 
  • Shin, Dong Hee; 
  • Kim, Do Hun; 
  • ... Im, Sang Hyuk; 
  • 외 3명
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초록

High-performance solid-state PbS quantum dot-sensitized solar cells (QD-SSCs) with stable 9.2% power conversion efficiency at 1 Sun condition are demonstrated by introduction of hybrid perovskite interlayer. The PbS QDs formed on mesoscopic TiO2 (mp-TiO2) by spin-assisted successive precipitation and anionic exchange reaction method do not exhibit PbSO4 but have PbSO3 oxidation species. By introducing perovskite interlayer in between mp-TiO2/PbS QDs and poly-3-hexylthiophene, the PbSO3 oxidation species are fully removed in the PbS QDs and thereby the efficiency of PbS QD-SSCs is enhanced over 90% compared to the pristine PbS QD-SSCs.

키워드

lead sulfide; quantum dots; sensitized solar cells; perovskite; passivation; ENHANCEMENT; CDSE
제목
High-Performance Solid-State PbS Quantum Dot-Sensitized Solar Cells Prepared by Introduction of Hybrid Perovskite Interlayer
저자
Heo, Jin Hyuck; Jang, Min Hyuk; Lee, Min Ho; Shin, Dong Hee; Kim, Do Hun; Moon, Sang Hwa; Kim, Sang Wook; Park, Bum Jun; Im, Sang Hyuk
DOI
10.1021/acsami.7b12046
발행일
2017-11-29
유형
Article
저널명
ACS Applied Materials & Interfaces
권
9
호
47
페이지
41104 ~ 41110