Supersonically Sprayed Zn2SnO4/SnO2/CNT Nanocomposites for High-Performance Supercapacitor Electrodes

  • Samuel, Edmund; 
  • Kim, Tae-Gun; 
  • Park, Chan-Woo; 
  • Joshi, Bhavana; 
  • Swihart, Mark T.; 
  • ... Yoon, Sam S.
Citations

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113

초록

In this study, we demonstrate rapid and facile supersonic cold spray deposition of Zn2SnO4/SnO2/CNT nano-composite supercapacitor electrodes with promising combinations of power and energy density. Cyclic voltammetry confirmed the capacitive behavior of the optimized electrode, with specific capacitance reaching 260 F.g(-1) at a current density of 10 A.g(-1). We attribute this high performance to the optimal combination of CNT (carbon nanotube; double-layer capacitance) and Zn2SnO4/SnO2 (pseudocapacitance) properties. The mesoporous and accessible surface of the CNT significantly contributed to the excellent retention (approximately 93%) of the specific capacitance after 15000 galvanostatic charge/discharge cycles. In addition, the supercapacitor exhibited a remarkable energy density, electrochemical properties, and mechanical stability. The materials and approach presented here can enable

키워드

Cold spray technique; Supercapacitor; Zn2SnO4; CNT; Nanocomposite; DOUBLE-LAYER CAPACITANCE; TRANSITION-METAL OXIDES; ELECTROCHEMICAL PROPERTIES; SURFACE-AREA; CARBON; NANOPARTICLES; NANOSTRUCTURES; NETWORK; ANODE
제목
Supersonically Sprayed Zn2SnO4/SnO2/CNT Nanocomposites for High-Performance Supercapacitor Electrodes
저자
Samuel, Edmund; Kim, Tae-Gun; Park, Chan-Woo; Joshi, Bhavana; Swihart, Mark T.; Yoon, Sam S.
DOI
10.1021/acssuschemeng.9b02549
발행일
2019-08-19
유형
Article
저널명
ACS Sustainable Chemistry & Engineering
권
7
호
16
페이지
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