Supersonically Sprayed Zn2SnO4/SnO2/CNT Nanocomposites for High-Performance Supercapacitor Electrodes

  • Samuel, Edmund
  • Kim, Tae-Gun
  • Park, Chan-Woo
  • Joshi, Bhavana
  • Swihart, Mark T.
  • ... Yoon, Sam S.
Citations

WEB OF SCIENCE

105
Citations

SCOPUS

111

초록

In this study, we demonstrate rapid and facile supersonic cold spray deposition of Zn2SnO4/SnO2/CNT nano-composite supercapacitor electrodes with promising combinations of power and energy density. Cyclic voltammetry confirmed the capacitive behavior of the optimized electrode, with specific capacitance reaching 260 F.g(-1) at a current density of 10 A.g(-1). We attribute this high performance to the optimal combination of CNT (carbon nanotube; double-layer capacitance) and Zn2SnO4/SnO2 (pseudocapacitance) properties. The mesoporous and accessible surface of the CNT significantly contributed to the excellent retention (approximately 93%) of the specific capacitance after 15000 galvanostatic charge/discharge cycles. In addition, the supercapacitor exhibited a remarkable energy density, electrochemical properties, and mechanical stability. The materials and approach presented here can enable

키워드

Cold spray techniqueSupercapacitorZn2SnO4CNTNanocompositeDOUBLE-LAYER CAPACITANCETRANSITION-METAL OXIDESELECTROCHEMICAL PROPERTIESSURFACE-AREACARBONNANOPARTICLESNANOSTRUCTURESNETWORKANODE
제목
Supersonically Sprayed Zn2SnO4/SnO2/CNT Nanocomposites for High-Performance Supercapacitor Electrodes
저자
Samuel, EdmundKim, Tae-GunPark, Chan-WooJoshi, BhavanaSwihart, Mark T.Yoon, Sam S.
DOI
10.1021/acssuschemeng.9b02549
발행일
2019-08-19
유형
Article
저널명
ACS Sustainable Chemistry & Engineering
7
16
페이지
14031 ~ +