Liquid-Liquid Equilibria for the Ternary Systems of Perfluamine plus Hydrofluoroether plus Benzene, Toluene, or Xylene at 298.15 K or 313.15 K

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초록

A fluorous biphasic system consists of a fluorinated solvent and an organic solvent. The mutual solubility data of fluorous biphasic systems were analyzed for common organic solvents such as benzene, toluene, and xylene with perfluamine. Fluorous/organic amphiphilic ether solvents such as HFE7300 and HFE7500 were added to the fluorous biphasic system. The equilibrium tie lines for ternary systems were determined at two different temperatures, and the equilibrium data sets were correlated with the nonrandom two-liquid and universal quasichemical models.

키워드

TRANSITION-METAL CATALYSISFLUOROUS BIPHASIC SYSTEMIMMOBILIZATION PRINCIPLEPRACTICAL APPLICATIONMEDIAMIXTURESALKENES
제목
Liquid-Liquid Equilibria for the Ternary Systems of Perfluamine plus Hydrofluoroether plus Benzene, Toluene, or Xylene at 298.15 K or 313.15 K
저자
Lee, Tae GyuSong, Kwang HoChoe, Jaehoon
DOI
10.1021/je400592a
발행일
2013-11
유형
Article
저널명
Journal of Chemical and Engineering Data
58
11
페이지
3130 ~ 3136