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초록
Treatment of sulfoxides with the HfCl4/Zn system in acetonitrile at room temperature has been shown to provide the corresponding sulfides in high yields. This new methodology is highly chemoselective, tolerating several functional groups such as -Br, -Cl, -OCH3, -CHO and double bond.
키워드
sulfoxide; zinc; hafnium(IV) chloride; sulfide; deoxygenation; AMINE-N-OXIDES; MILD; REDUCTION; SELENOXIDES
- 제목
- A facile and efficient procedure for the deoxygenation of sulfoxides to sulfides with the HfCl4/Zn system
- 저자
- Yoo, Byung Woo; Yu, Bo Ran; Yoon, Cheol Min
- 발행일
- 2015-07-04
- 유형
- Article
- 권
- 36
- 호
- 4
- 페이지
- 358 ~ 363