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Metal-Free Transamidation of Primary Amides using Trimethylsilyl Chloride
- Yu, Subeen;
- Song, Kwang Ho;
- Lee, Sunwoo
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WEB OF SCIENCE
24Citations
SCOPUS
26초록
A metal-free transamidation of primary amides was developed. Trimethylsilyl chloride (TMSCl) acted as the activator in transamidation. In the presence of TMSCl, primary amides reacted with primary amines to yield transamidated secondary amides in NMP solvent. The transamidation of benzamide with secondary amines for the formation of tertiary amides succeeds in an NMP/CHCl3 solvent mixture.
키워드
transamidation; metal-free chemistry; amides; amines; trimethylsilyl chloride; CATALYZED TRANSAMIDATION; EFFICIENT CATALYST; CARBOXYLIC-ACIDS; SECONDARY AMIDES; CARBOXAMIDES; AMINES; SOLVENT; UREAS; COMPLEX
- 제목
- Metal-Free Transamidation of Primary Amides using Trimethylsilyl Chloride
- 저자
- Yu, Subeen; Song, Kwang Ho; Lee, Sunwoo
- 발행일
- 2019-09
- 유형
- Article
- 권
- 8
- 호
- 9
- 페이지
- 1613 ~ 1616
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 4 페이지
- ISSN
- E 2193-5815
P 2193-5807