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Metal Effects on the Thermal Decomposition of exo-Tetrahydrodicyclopentadiene
- Park, Sun Hee;
- Kim, Joongyeon;
- Chun, Jeong Hwan;
- Chung, Wonkeun;
- Kim, Sang Gon;
- ... Han, Hogyu;
- 외 5명
WEB OF SCIENCE
21SCOPUS
22초록
We investigated the thermal decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of various metals, Ti, SS316, SS304, Fe, Ni, and Cu. It was found that conversion of exo-THDCP was faster in the presence of metals as compared to in their absence. The order of the metal effects on the increase in the conversion of exo-THDCP was Ti < SS316 < SS304 < Fe < Ni < Cu. The metal-induced increase in the conversion of exo-THDCP was higher at the higher temperature. In addition, the metal-induced increases in the rates of C5-9, C15-, and C-sd product formations were higher than those of <= C-4 and C10-14. The composition and crystallinity of metal surfaces were found to be associated with the distinct metal effects on the thermal decomposition of exo-THDCP.
키워드
- 제목
- Metal Effects on the Thermal Decomposition of exo-Tetrahydrodicyclopentadiene
- 저자
- Park, Sun Hee; Kim, Joongyeon; Chun, Jeong Hwan; Chung, Wonkeun; Kim, Sang Gon; Lee, Chang Hun; Chun, Byung-Hee; Han, Jeong Sik; Jeong, Byung Hun; Han, Hogyu; Kim, Sung Hyun
- 발행일
- 2013-03-27
- 유형
- Article
- 권
- 52
- 호
- 12
- 페이지
- 4395 ~ 4400
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 6 페이지
- ISSN
- E 1520-5045
P 0888-5885