Conformal CEI formation induced by oxygen-functionalized conductive agents on Mn-rich olivine cathodes

  • Ko, Eunseo; 
  • Lee, Seojin; 
  • Kim, Jaehwan; 
  • Kim, Minseo; 
  • Kim, So Hee; 
  • ... Yu, Seung-Ho; 
  • 외 3명
Citations

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2

초록

LiMnxFe1-xPO4 (LMFP, 0 < x < 1) suffers from low electronic conductivity and Mn dissolution. Reduced graphene oxide (rGO) improves electronic conductivity and acts as a sacrificial oxygen source, enabling conformal CEI formation via oxidation of surface functional groups, thereby enhancing the interfacial stability and cycling performance of LMFP electrodes.

키워드

Lithium Ion; Manganese; Polyvinylidene Fluoride; Oxygen; Electric Conductivity; Graphene; Iron Compounds; Manganese; Manganese Compounds; Oxygen; Reduced Graphene Oxide; Cycling Performance; Electronic Conductivity; Functionalized; Interfacial Stabilities; Mn Dissolutions; Oxygen Sources; Reduced Graphene Oxides; Stability Performance; Surface Functional Groups; Cathodes; Conventional Carbon Additive; Drug Additive; Electrolyte Salt; Graphene Oxide; Lithium Ion; Manganese; Polyvinylidene Fluoride; Unclassified Drug; Oxygen; Article; Capacity Retention; Cathode Electrolyte Interphase; Cyclic Voltammetry; Electron Conduction Pathway; Galvanostatic Charge Discharge; High Resolution Transmission Electron Microscopy; Human; Impedance Spectroscopy; Inductively Coupled Plasma Optical Emission Spectroscopy; Raman Spectrometry; Scanning Electron Microscopy; Two-dimensional Imaging; Warburg Effect; X Ray Diffraction; X Ray Photoemission Spectroscopy; Article; Cathode Electrode; Conductance; Controlled Study; Dissolution; Electrode; Oxidation
제목
Conformal CEI formation induced by oxygen-functionalized conductive agents on Mn-rich olivine cathodes
저자
Ko, Eunseo; Lee, Seojin; Kim, Jaehwan; Kim, Minseo; Kim, So Hee; Sung, Yung-Eun; Yu, Seung-Ho; Moon, Joonhee; Park, Jungjin
DOI
10.1039/d5cc02422f
발행일
2025-07-24
유형
Editorial Material
저널명
Chemical Communications
권
61
호
61
페이지
11473 ~ 11476