A protecting group-free divergent synthesis of natural benzofurans via one-pot synthesis of 2-bromo-6-hydroxybenzofurans

  • Sivaraman, Aneesh
  • Harmalkar, Dipesh S.
  • Kang, Jiyoon
  • Choi, Yongseok
  • Lee, Kyeong
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초록

2-Bromo-6-hydroxybenzofurans are potentially versatile intermediates for the divergent synthesis of numerous benzofuran-based natural products and their analogues. Herein we report the first one-pot strategy for the efficient synthesis of 2-bromo-6-hydroxybenzofurans. The present protocol provides shorter routes for the synthesis of moracins M, N, O and P; gramniphenols F and G; and morunigrol C using a protecting group-free approach.

키워드

EFFICIENT TOTAL-SYNTHESIS1ST TOTAL-SYNTHESISINTRAMOLECULAR CYCLIZATIONMORACIN OCICERFURAN2-ARYLBENZOFURANSINHIBITORSPHYTOALEXINDERIVATIVESCONVENIENT
제목
A protecting group-free divergent synthesis of natural benzofurans via one-pot synthesis of 2-bromo-6-hydroxybenzofurans
저자
Sivaraman, AneeshHarmalkar, Dipesh S.Kang, JiyoonChoi, YongseokLee, Kyeong
DOI
10.1039/c8ob03102a
발행일
2019-02-28
유형
Article
저널명
Organic & Biomolecular Chemistry
17
8
페이지
2153 ~ 2161