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Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(II) metal-organic framework
- Jeong, Euna;
- Lee, Woo Ram;
- Ryu, Dae Won;
- Kim, Yeonga;
- Phang, Won Ju;
- ... Hong, Chang Seop;
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An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N-2, H-2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units.
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- Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(II) metal-organic framework
- 저자
- Jeong, Euna; Lee, Woo Ram; Ryu, Dae Won; Kim, Yeonga; Phang, Won Ju; Koh, Eui Kwan; Hong, Chang Seop
- 발행일
- 2013
- 유형
- Article
- 권
- 49
- 호
- 23
- 페이지
- 2329 ~ 2331