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Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline
- Park, Sun Hee;
- Park, Yumi;
- Han, Jeong Sik;
- Jeong, Byung Hun;
- Han, Hogyu;
- 외 1명
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6초록
We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.
키워드
SINK JET FUELS; OIL (RCO/LCO)-DERIVED STABILIZERS; SIMILAR HYDROCARBON MIXTURES; HIGH-TEMPERATURE STABILIZERS; SOLID DEPOSITS; N-DODECANE; MODEL; JP-8; FLUOROTYROSINES; DECOMPOSITION
- 제목
- Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline
- 저자
- Park, Sun Hee; Park, Yumi; Han, Jeong Sik; Jeong, Byung Hun; Han, Hogyu; Kim, Sung Hyun
- 발행일
- 2015-01
- 유형
- Article
- 저널명
- Energy & Fuels
- 권
- 29
- 호
- 1
- 페이지
- 16 ~ 20