Electrochemical characterization of Raney nickel electrodes prepared by atmospheric plasma spraying for alkaline water electrolysis

  • Kim, Ji-Eun
  • Bae, Ki-Kwang
  • Park, Chu-Sik
  • Jeong, Seong-Uk
  • Baik, Kyeong-Ho
  • ... Lee, Ki-Bong
  • 외 3명
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47

초록

A Raney Ni electrode was prepared by the simple and economical atmospheric plasma spraying method. It showed excellent performance for hydrogen evolution reaction (HER), as indicated by a Tafel slope of 54 mV/dec and overvoltage of 108 mV at 300 mA/cm(2). The Ni-Al alloy coating contained a NiAl phase, which has a very slow Al leaching rate in alkaline solution. H-2 heat treatment of the electrode enhanced the uniformity of Al distribution in the coating and adhesion of the coating to the substrate. However, the HER performance did not improve and the electrode was rendered more structurally vulnerable to deactivation. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

키워드

Water electrolysisAlkaline electrolysisRaney nickelHydrogen evolution reactionElectrode deactivationAtmospheric plasma sprayingHYDROGEN EVOLUTION REACTIONREDUCED GRAPHENE OXIDENIELECTROCATALYSTNANOPARTICLES
제목
Electrochemical characterization of Raney nickel electrodes prepared by atmospheric plasma spraying for alkaline water electrolysis
저자
Kim, Ji-EunBae, Ki-KwangPark, Chu-SikJeong, Seong-UkBaik, Kyeong-HoKim, Jeong-WonKang, Kyoung-SooLee, Ki-BongKim, Young-Ho
DOI
10.1016/j.jiec.2018.10.010
발행일
2019-02-25
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
70
페이지
160 ~ 168