상세 보기
초록
Charge-compensated zinc metallocenes of types [(eta(3)-C2B9H10)(2)Zn]-[(eta(1)-NMe2)ZnEt](2) (5) and [{eta(3)-(Me)C2B9H9}(2)Zn][(eta(1)-NMe2)-ZnEt](2) (6) were produced by reacting sigma-/pi-chelating aminoalkyl dicarbollides, 7-Me2N(H)CH2-7,8-C2B9H11 (1) and 7-Me2N(H)CH2-8-Me-7,8-C2B9H10 (2), with diethylzinc. Zincocene 5 proved to be an excellent synthon for the formation of dicarbollide-based sigma-/pi-type constrained Ru and Ni complexes.
키워드
CRYSTAL-STRUCTURE; SANDWICH COMPLEX; CHEMISTRY; FERROCENE; ANALOGS; ION
- 제목
- Charge-compensated Zn metallocenes with sigma-/pi-chelating carboranyl ligands for the formation of constrained geometry Ru(II) and Ni(II) complexes
- 저자
- Lee, Jong-Dae; Han, Won-Sik; Kim, Tae-Jin; Kim, Sang Hern; Kang, Sang Ook
- 발행일
- 2011
- 유형
- Article
- 권
- 47
- 호
- 3
- 페이지
- 1018 ~ 1020