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초록
The reaction of Baylis-Hillman adducts with iodobenzenes using commercially available palladium-on-carbon as a catalyst under solvent-free conditions afforded the corresponding coupling products, alpha-benzyl-beta-keto esters, in high to excellent yields. The reactions are very efficient.
키워드
Baylis-Hillman adduct; Heck reaction; palladium-on-carbon; iodobenzenes; alpha-benzyl-beta-keto esters; LIGAND-FREE; SONOGASHIRA REACTION; EFFICIENT SYNTHESIS; COUPLING REACTIONS; ALPHA-ARYLATION; BOND FORMATION; ARYL IODIDES; COPPER-FREE; PALLADIUM; CARBON
- 제목
- Heck Reaction of Baylis-Hillman Adducts with Iodobenzenes Using a Catalytic Amount of Pd/C under Solvent-Free Conditions
- 저자
- Kim, Hyun-Soo; Lee, Sang-Jin; Choi, Boram; Yoon, Cheol Min
- 발행일
- 2012-10
- 유형
- Article
- 저널명
- Synthesis
- 권
- 44
- 호
- 20
- 페이지
- 3161 ~ 3164