Hybrid effect of doped and de-doped poly(3-methylthiophene) nanowires with CdSe/ZnS quantum dots: Nanoscale luminescence variation

  • Lee, Sunmi; 
  • Lee, Youg-baek; 
  • Park, Sung-yeoun; 
  • Lee, Hyunsoo; 
  • Kim, Jeongyong; 
  • ... Joo, Jinsoo; 
  • 외 1명
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초록

Doped and de-doped poly(3-methylthiophene) (P3MT) nanowires (NWs) were synthesized through electrochemical polymerization and functionalized CdSe/ZnS quantum dots (QDs) with blue and green emissions were homogeneously attached to the NW surfaces. The photoluminescence (PL) spectra of the QDs/P3MT single NWs indicated a drastic enhancement of PL intensity for both doped and de-doped NWs owing to the energy transfer effect from QDs to NWs. The QDs/de-doped P3MT NWs exhibited higher energy transfer efficiency because of a reduced screening effect for energy transfer, which was confirmed by a decrease in the exciton lifetime of the QDs, determined from time-resolved PL decay curves. (C) 2012 Elsevier B.V. All rights reserved.

키워드

Poly(3-methylthiophene); Nanowire; CdSe/ZnS quantum dot; Energy transfer; Photoluminescence; ENERGY-TRANSFER; CONJUGATED POLYMERS; OPTICAL-PROPERTIES; PHOTOLUMINESCENCE; NANOTUBES
제목
Hybrid effect of doped and de-doped poly(3-methylthiophene) nanowires with CdSe/ZnS quantum dots: Nanoscale luminescence variation
저자
Lee, Sunmi; Lee, Youg-baek; Park, Sung-yeoun; Lee, Hyunsoo; Kim, Jeongyong; Lee, Kwang-Sup; Joo, Jinsoo
DOI
10.1016/j.synthmet.2012.12.025
발행일
2013-01-15
유형
Article
저널명
Synthetic Metals
권
164
페이지
22 ~ 26