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초록
Microwave irradiation has been shown as a simple and effective method for stereocomplexation of polylactide with various molecular weights. The thermal and non-thermal effects of microwave irradiation effectively support the stereocomplexation in a relatively short time. Surprisingly, the linear stereocomplex polylactide generated using microwave irradiation has particular thermal stability compared to that prepared using other methods. The microwave irradiation is also suitable for various types of polylactide-based materials. (c) 2013 Society of Chemical Industry
키워드
microwave irradiation; melt stability; polylactide; stereocomplex; ENANTIOMERIC POLY(LACTIC ACID)S; HIGH-MOLECULAR-WEIGHT; POLY(L-LACTIDE)/POLY(D-LACTIDE) STEREOCOMPLEX; POLY(D-LACTIC ACID); POLY(L-LACTIC ACID); SUPERCRITICAL-FLUID; ORGANIC-SYNTHESIS; MELT STABILITY; CRYSTALLIZATION; DEGRADATION
- 제목
- Stereocomplex formation of polylactide using microwave irradiation
- 저자
- Purnama, Purba; Kim, Soo Hyun
- DOI
- 10.1002/pi.4581
- 발행일
- 2014-04
- 유형
- Article
- 권
- 63
- 호
- 4
- 페이지
- 741 ~ 745