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Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged M-II (M = Mn, Ni) coordination polymers
- Lim, Kwang Soo;
- Song, Jeong Hwa;
- Kang, Dong Won;
- Kang, Minjung;
- Eom, Sunhwi;
- ... Hong, Chang Seop;
- 외 1명
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22초록
M-II (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.
키워드
HIRSHFELD SURFACE; CO-LIGANDS; COMPLEXES; FRAMEWORK; COPPER(II); NICKEL(II); CONVERSION; NETWORKS; BEHAVIOR; MN(II)
- 제목
- Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged M-II (M = Mn, Ni) coordination polymers
- 저자
- Lim, Kwang Soo; Song, Jeong Hwa; Kang, Dong Won; Kang, Minjung; Eom, Sunhwi; Koh, Eui Kwan; Hong, Chang Seop
- 발행일
- 2018-01-21
- 유형
- Article
- 권
- 47
- 호
- 3
- 페이지
- 845 ~ 851
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 7 페이지
- ISSN
- E 1477-9234
P 1477-9226