Ionic block copolymer doped reduced graphene oxide supports with ultra-fine Pd nanoparticles: strategic realization of ultra-accelerated nanocatalysis

  • Cho, Kie Yong; 
  • Yeom, Yong Sik; 
  • Seo, Heun Young; 
  • Kumar, Pradip; 
  • Lee, Albert S.; 
  • ... Yoon, Ho Gyu; 
  • 외 1명
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45
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50

초록

We synthesized an ultra-fine Pd nanocatalyst supported by ionic block copolymer doped reduced graphene oxide (Pd-PIBrGO) for ultra-accelerated nanocatalysis. This hybrid catalyst exhibited exceptionally advanced catalytic performance for the reduction of methylene blue using miniscule quantities of Pd-PIBrGO due to facilitated diffusion of reagents, resulting in full reduction within a few seconds and showing a 280-fold increase of the rate constant over Pd-rGO without ionic block copolymers.

키워드

Ionic block copolymer; graphene oxide; ultra0fine Pd nanoparticles; hybrid catalyst; METAL-ORGANIC FRAMEWORKS; CORE-SHELL NANOPARTICLES; ONE-POT; NANOCRYSTALS; REDUCTION; CATALYSIS; CHARGE; ARCHITECTURES; STABILITY; DESIGN
제목
Ionic block copolymer doped reduced graphene oxide supports with ultra-fine Pd nanoparticles: strategic realization of ultra-accelerated nanocatalysis
저자
Cho, Kie Yong; Yeom, Yong Sik; Seo, Heun Young; Kumar, Pradip; Lee, Albert S.; Baek, Kyung-Youl; Yoon, Ho Gyu
DOI
10.1039/c5ta06076a
발행일
2015
유형
Article
저널명
Journal of Materials Chemistry A
권
3
호
41
페이지
20471 ~ 20476