Chemical transformation of solution-processed Ag nanocrystal thin films into electrically conductive and catalytically active Pt-based nanostructures

  • Seong, Mingi
  • Kim, Hoyoung
  • Woo, Ho Young
  • Hossain, Md Ashraf
  • Ahn, Jun Hyuk
  • ... Oh, Soong Ju
  • 외 2명
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초록

Efficient methods for the controlled syntheses of metal nanocrystals are important for emerging electronics and catalysis applications. In this report, we present a solution-based method for the fabrication of Pt-coated Ag nanocrystal (NC) thin films through the use of ligand-exchange and electroless deposition. We successfully prepared uniform or bumpy Ag@Pt core/shell structures, as well as Ag-Pt alloy structures, through control of the reducing agents. We first report the Ag-Pt alloy structures can be synthesized by low-temperature and solution-based process of post treatment that exhibited high catalytic activity toward the hydrogen evolution reaction. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

키워드

Silver nanocrystalPt-Ag alloy structureElectroless depositionGalvanic displacementHydrogen evolution reactionONE-POT SYNTHESISENHANCED ELECTROCATALYTIC ACTIVITYHYDROGEN EVOLUTIONGALVANIC REPLACEMENTALLOY NANOPARTICLESREDUCTIONGOLDCOTRANSITIONDEPOSITION
제목
Chemical transformation of solution-processed Ag nanocrystal thin films into electrically conductive and catalytically active Pt-based nanostructures
저자
Seong, MingiKim, HoyoungWoo, Ho YoungHossain, Md AshrafAhn, Jun HyukKim, Soo-KilPaik, TaejongOh, Soong Ju
DOI
10.1016/j.jiec.2019.04.004
발행일
2019-08-25
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
76
페이지
388 ~ 395