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Palladium-Catalyzed Oxidative Aminocarbonylation by Decarboxylative Coupling: Synthesis of Alkynyl Amides
- Hwang, Jinil;
- Choi, Jinseop;
- Park, Kyungho;
- Kim, Wonyoung;
- Song, Kwang Ho;
- 외 1명
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33초록
Alkynyl amides were synthesized from a palladium-catalyzed coupling reaction of alkynyl carboxylic acids and amines under carbon monoxide. The reaction was conducted with palladium(II) acetate (5 mol-%) and silver(I) oxide (1.0 equiv.) in acetonitrile at 80 degrees C for 1 h. This method provides good to moderate product yields and good functional group tolerance towards ketone, ester, and nitrile groups.
키워드
Synthetic methods; Palladium; Carbonylation; Alkynes; Amides; ONE-POT SYNTHESIS; CARBOXYLIC-ACIDS; PROPIOLIC ACID; ARYL HALIDES; CARBON; CARBONYLATION; EFFICIENT; ESTERS; ALPHA; SP(2)
- 제목
- Palladium-Catalyzed Oxidative Aminocarbonylation by Decarboxylative Coupling: Synthesis of Alkynyl Amides
- 저자
- Hwang, Jinil; Choi, Jinseop; Park, Kyungho; Kim, Wonyoung; Song, Kwang Ho; Lee, Sunwoo
- 발행일
- 2015-04
- 유형
- Article
- 권
- 2015
- 호
- 10
- 페이지
- 2235 ~ 2243
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 9 페이지
- ISSN
- E 1099-0690
P 1434-193X