Significance of Hydrophilic Characters of Organic Dyes in Visible-Light Hydrogen Generation Based on TiO2

  • Lee, Su-Hyun
  • Park, Yiseul
  • Wee, Kyung-Ryang
  • Son, Ho-Jin
  • Cho, Dae Won
  • 외 3명
Citations

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초록

A series of dyes were synthesized to examine the roles of the hydrophilic characteristics of R in sensitized hydrogen generation by dyegrafted Pt/TiO2 under visible light irradiation. The hydrogen-generation efficiencies and optimum amounts of the dyes grafted to Pt/TiO2 were affected substantially by the hydrophilic and steric effects of R; moderately hydrophilic DEO1 and DEO2 showed higher sensitization activity at a lower loading than hydrophobic D-H.

키워드

SENSITIZED SOLAR-CELLSPHOTOCATALYTIC DECOMPOSITIONTITANIUM-DIOXIDEWATER CLEAVAGEEVOLUTIONIRRADIATIONCONVERSIONCOMPLEXESDYNAMICSFILMS
제목
Significance of Hydrophilic Characters of Organic Dyes in Visible-Light Hydrogen Generation Based on TiO2
저자
Lee, Su-HyunPark, YiseulWee, Kyung-RyangSon, Ho-JinCho, Dae WonPac, ChyongjinChoi, WonyongKang, Sang Ook
DOI
10.1021/ol9026182
발행일
2010-02-05
유형
Article
저널명
Organic Letters
12
3
페이지
460 ~ 463