Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units

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초록

A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.

키워드

calixarenethiacalixarenestrontiumvoltammetryion recognitionBINDING-PROPERTIESMETAL-IONSDERIVATIVESRECEPTORSTHIACALIXARENESCOMPLEXATIONEXTRACTION
제목
Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units
저자
Kim, Tae HyunKim, HasuckLee, Joung HaeKim, Jong Seung
발행일
2008-03-20
유형
Article
저널명
Bulletin of the Korean Chemical Society
29
3
페이지
620 ~ 622