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Microporous Lanthanide-Organic Frameworks with Open Metal Sites: Unexpected Sorption Propensity and Multifunctional Properties
- Lee, Woo Ram;
- Ryu, Dae Won;
- Lee, Jin Wuk;
- Yoon, Jung Hee;
- Koh, Eui Kwan;
- ... Hong, Chang Seop
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66초록
Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd3+ to Gd3+, which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments.
키워드
GAS-ADSORPTION; THERMAL-STABILITY; HYDROGEN STORAGE; H-2 ADSORPTION; CARBON-DIOXIDE; BINDING; AFFINITIES; CATALYSIS; CHANNELS; OXIDE
- 제목
- Microporous Lanthanide-Organic Frameworks with Open Metal Sites: Unexpected Sorption Propensity and Multifunctional Properties
- 저자
- Lee, Woo Ram; Ryu, Dae Won; Lee, Jin Wuk; Yoon, Jung Hee; Koh, Eui Kwan; Hong, Chang Seop
- 발행일
- 2010-06-07
- 유형
- Article
- 권
- 49
- 호
- 11
- 페이지
- 4723 ~ 4725
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 3 페이지
- ISSN
- E 1520-510X
P 0020-1669